First of all it might not be that easy to backup a SQLEXPRESS database and restore it on a SQL 2005 Server. I have tried it a couple of times and it fails for not finding the correct paths. Searching the Net it seems that this is a limitation of the SQLEXPRESS.
Do you run into problems when you are retoring the database onto the SQL server, or do you manage to do that?
UPDATE: I deleted my original text here, as Martin gave a better explanation. We seemed to write it at the same time, look at the post time 